Here's an article that comments on why many (not all, but many) are uncomfortable about money:
How banks should talk to women - MSN Money
I've been fortunate that my financial advisor whom I've known for over 20 years has been patient, answers questions, and doesn't talk down to me. He wasn't someone that expected me to have tons of money to start out and helped me get started investing. I'm not rich, but we are sure comfortable and part of it is because of his patience and advice.